【行业标准】 进出口蜂王浆中多种菊酯类农药残留量检测方法

民格检标
S3/H 2575-20 0
进出口峰王多种药酯类
衣药戏留堂检测方法
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2010-12:01 安
太标准按照GBT12009路出规赠年标准中间家认证认可监督管家梯本标准商草单位，中华人支共订服渐治中商检验得按间。本探准主要起章人，工紫斑、谢安、核院处学们、姚新。http：//foodmate.nets/T25752010
，装围
进家种
SN/T2575-2010
标温就「峰“聚中联只绅酷用京调银制霸雅鼠菊情科氯寳菊氯香菊酷氟安食药凰能成菊润澳食菊衣药然南的标包游盗方法，本标准彩历于蜂正浆中医莱南丽、中气彩断、最氟款装酯、新药酷、氣实氧贵、氯装防、收氧装瑞线临鼠酷衣药消等的制宝
P防法腺裂
武择中的菊头农药残科经止好内调，：外科比泥合漆剂提职，用弗罗业宿七内相举职社净化（州鱼部电学东测牢萃洲楚外添量：3：试剂和料
除州行说测外所！门均为分新街，车普求或去离子水3,1醚;表溅级
3、2正炼农戏缴、
商闻表酸级，
3无水硫酸销，灼烧十用在下梯器内我室案湖·储于密封瓶中备用，3送米雍带，下氧第码、点氮凯菊糖、特后，斌氯院菊、叙舒南酯、鼠胺织类醋颜战菊情氛标准家质：纯康人十会中尔教以谢录菊中点气脂，汉御配氯氨物密酷成鼠菊能标难落游分别准确务收进带你汇核：配或效立为）m！，的标准储危液。限品别用店统稀释混合盈湿当然领的台家泽下件神现奖单减十面新笨料！，）：中，便！！能社与镇约0mm无水硫酸层用正品饶游活恒率取准
设谐机设备
1气利他仪：等然
4.2避鸿混线
手：商心视转速A下6n，
心氮议
4.5嵌转族发靠。
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FR/7 2875-.-2010
！试样制者与保存
5、！制样制备
最代表性刘品约，将用为房！，中单净器·密时，并标明际记5.2试样保程
于客以保有。「制样是中中率，义染波发牛新测物残留最的变化6测筹骤
称堰成伴精雄到灿求竭限m薛mm，人20 m正们烧一酮一本积是：以4o/mi离心3m将上层有机有转移人案筑款中。没清中训人坛“内！中、本积民）据合溶剂·互复投取一次个上展有利而该下求降减学
淡缩瓶中戏留物用3止欢学个净资，资质需多活机取科.8）中，图！m！开烯渐洗弃去流出波问m！滤合深润洗脱，收集洗脱液玻骗商件中在水中科短出按得装个偿解”准容军05m，供汽相件谱测定。
相色谱察科
需生0！爽年含，内径0.顺厚成机者，仅谱性湿:保华！！了！：法率了0 保持1m20/minbl
的升谢于势：
性可温变:20
洲群度2。
裁t.ak 9 .m 2 m + m in?
逆献：2
8）认样方武不分流避样计阔，
63.2免谱测定
极屠群滚中备种毕自最，器的准在降，标耀性耀滋和样被山行种菊消的呵成值的成在议牌测定的俊比范用问：安：！落液详液等体飘寳拥进样测是，在！然伴谱条社联举辆酷的保计时可的为？产：每净效为！务min氟鼠第的保留间纳为心氮名年核然信保密-，：中心6m筑氯商客导购体的保的时制约16 6 mim、16.？r、3.4ir:含表名2的化路时间药为175 rmin、17.6 nir、17,8 tmir胶鼠将备异纳体第绿间到间绝为：）军皮菊脂舒体的保留时间约19.9rn.20m证激酷得鼠用送m作品的自谱图移见际录B中图B1httn
综不加试择处，的换上试测知心费行总1酷款计算
出色数据外理欧价求接式（）觉试半中金赠的然留含资：axy
神激，单嘉
9n/2 2575 -2010
择波中务能药品热动（（机车品计算备年构体闪峰积之和）深解「作整中台种菊基的泽暖：中成贸为码睿汉最终样液宝容体积位司餐升（）标工作液中络需商间制行品体的要脂领计算务外构体的峰双和）：最终液研代表的点格点：单阅票家法的测定低限和间收誉
测定您限
本大法的测定低限为o1mx8。
回收券
祥品的加浓说收浓的密您报贴心家！样品拍滋a滋席摄源游的实验嫩据武
联紫盛靠
然素常药酸
谢线来
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农药称
氮尔荔哈
缅胺氧作
部皮的谱
温却的
群的密深实得激病（）
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腊漆康
【童裂学附聚
9动菊随类农数中技出遥用各择、化学公式、心A食寄脑意5#/25752010
表A种菊醒滋农然设点通用檬，能单分子式S号信息中文道市名科
联本商
能之萄靠
氮尔罪
仪察肾
浪子啡
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3/室 2575---2019
！50m
1000 -
欧莱袭酯；
年河能：
数案府
氯东蕲
氯响能！
氧药些川，
氣氧鼠装靠：
忽能，
氣酯川；
菊醋Ⅲ；
微胺智菊酯；
滋菊，
丧料酯循上：
镇菊鲱
料附）
标准潮的色谱阁
图B19配热家家标准物通相的图
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S/T25752010
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Determinatior ot rmultipie gyrethroid residuesin royaljally fr irnport and export1Seome
Tnis sterdard specif es the mcther for detein.rul or f multiple pyethraic residues in royal jelly tcrimport anic export by gas chroiratography(Gc).This tal tdartd is applicable to rdetermination and confirmation of Bifant:hrin, Fer:preoathrin, larhda-Cyhalothrin.Perrnethrir,Cytluthrin,Cypcrrnethrin,Fiuvalerate.Fenvaierats,Deitamet:rin residues inroyal-ially.
2Freineipio
Wulritie ryrethroic residues are extractec frorm the sample with n-hexane-acetonecT I t. v/v), Theextrai is cleaned p with lcrisll cartridge. I nally it is anterrnined by GcEca and guartitiod byextsrral eradard msthnd,
3Haagents aromatoriais
Ulnlnss ctherwise smecifiert all reagents anoid be analytiraly pure, water ahould be redistilled cr daicni2ad
3. 1 Ether:tiPLC giadebzxz.net
3.2 N.nexane HFI.C grade.
3. #Aeetcne,HPIc grade
3. 4Sodiun chlarida.
3. fsucum sulfate anhydrous; lerite tor 4 h at io t. ,eoot fa rnor temgorature in desiscaror enkeap ir a tightly elased containar.3.6i'athrin.fanpropathrin.lantun cyhealth: n.ennerhrin,syfluthtin,cyrermethrin,flualereie.hervaiera.e.deltamethrin stanrlards.turiiy sr ay Spn :ole: A. : in the armex A,8
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SN/2575--2010
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Gas chromatograrty (c).equipped with electron capture detector (EcD)4.2Vortex imisar.
c.Cortifuge:5ox:/min
a.4Nitrnigjen evapuratorwithheareci batf,taalary vacuur avaporetor.preparet on ane Btorwge
5.! Proparation oi tent samgleFakea aprrpriertely tDo g f ropresentativt: sernple,ixed tharoughly. Then the hemogerizet samp!is placars in a elean rrtsainer aw the test tampie, whia is sealed ard labaled.5.2stuags cfto:sarnglm
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9n/1 7575--2010
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Cissoiv the resiclue in the troncarn,ng luli iwice w th :s mi n-hexarie an transte? tre seutinintetheflarisil spt cariridge (3.B:.Wh fhnt:wthndneraneather(31.V/v)in abote!Vollme taf re ml. thatter the wrashirg Fea.ic Inr To ! enrifugt: imkus ad gcntly rvupxrate t: tosryitas by niirogem evaporaror at4s h:rns n. s ialuey in a.m.phnxare aoluticr andxsty tut he derarrmination by Gt..taDarmolim
G.3.1G, operatin corditien
Chrcrnatogrephir: cslumn Hpb -fugac inz. apillary tturp.ay r x o. 32 rn(i. xc um or equivalent,
0 G/ni
b)Colurnternparature:uc(imrin2800min)
)Irjecten port temperatne:270 d: Ietector temperature: 325 C Carrier gas: Nitrogen (purisy a. Suo.+:tie rare :t sarrier gas,z. 0 ml/rin. Flow rate irake up.eo rni./rgin;
njesetinn rnroe:2 ul.
Jnjacrinn yslums:Splitlrasn.pursj: tiru.o. A. aint&..2Chartificarior
Areordin to the approxinate tonoantrntinns t muHpie: myrtthrvid in anpin soiution, select thestaridar! working vlurtitn with cirrii mi rcsr, r. that t arile iurtion. The respense of thnenalyte in tna taridard workivig srstutior nn: n o\pinsalution shoud! bewithir:tha line ang o!tre irstruient detelion Th stadar orkir wliien thtk! br iniletd afore onc betwan thsinctisns f sarnple soluticn oi nl vshrrr, ti n: l abov ae sgaistirn corsiiton,tie retertiotimr of Fifenthrin is about 2.9 n n,tn rte at aprorattrir is about 13.6 mir. tretrrtign trne af Lanbdo. Cynelothrirt is akust't dl, c rirtla irlahugn tirmes or Peirrethrin :sorme ares10
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