GB/T 19648-2005 Determination of 446 pesticide residues in fruits and vegetables by gas chromatography-mass spectrometry and liquid chromatography-tandem mass spectrometry

This standard specifies the determination method of 446 pesticide residues in fruits and vegetables by gas chromatography-mass spectrometry and liquid chromatography-tandem mass spectrometry. This standard is applicable to the determination of 446 pesticide residues in fruits and vegetables such as apples, pears, citrus, bananas, grapes, pineapples, kiwis, cabbages, tomatoes, cucumbers, green peppers, spinach, cauliflower, celery, beans, carrots, potatoes, and bamboo shoots. The method detection limit of this standard is 0.000 2mg/kg to 0.600 0mg/kg. GB/T 19648-2005 Determination of 446 pesticide residues in fruits and vegetables by gas chromatography-mass spectrometry and liquid chromatography-tandem mass spectrometry GB/T19648-2005 Standard download decompression password: www.bzxz.net

1cs67.02c
National Standard of the People's Republic of China
GB/T19648—2005
Method for determination of 446 pesticide residues in fruits and vegetables-GC-MS and LC-MS LC-MS-S
2005-02-04Release
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of ChinaStandardization Administration of China
2005-08-01Implementation
GB/r19646—2055
Current Standard Introducing Documents
Trial Judgment and MaterialsWww.bzxZ.net
Trial Detailed Preparation and Preservation
Xie Dingbu Qiang
Drilling Instrument
Precision
Breakdown A (Information Station Directory: 446 New Chinese Names of Pesticides, Method Format: 1 Limit, Office, Selection and Mixing Standard Depth Separation Strategies Table..
Appendix System (information requirements)
G: MS measurement of a batch of pesticides, standard chemical storage retention time, gold ion, fixed ion and the ratio of the fixed ion to the fixed ion ... ... ... time table (data requirements) (Appendix: MA to FA, HCD group pesticide selection control high monitoring division (strong resistance requirements) foreign substances in the selected rate of base monitoring (-MS Figure 1M5M determination of the cross-drug theft detection, micro-energy group voltage retention time requirements (information requirements)
Appendix F material system) standard LC-MSMS total ion theft list Appendix G (information network) 440 issued by the grid table Appendix H (information appendix) 445 minutes pesticide English Chinese name comparison review 22 || tt||GB/T19648—2035
The appendix of this standard is the appendix of the radiation safety record and the appendix of the scientific record. This standard is issued by the People's Republic of China. This standard is issued by the People's Republic of China and other state-owned enterprises, the People's Republic of China and the State Administration for Market Regulation. The main authors of this standard are: Ni Tongjie, Fan Benlin, Zhang Jinxi, Liu Shuishan. Gao Xizhong, Xue Xuemin, Bei Chiping, Xie Caixing, and the regional standard is the first national standard. 1 Scope
Determination of 446 pesticides in fruits and vegetables by gas chromatography-mass spectrometry and liquid chromatography-tandem mass spectrometry GB/T19 648—2005
This standard specifies the determination method of 145 kinds of pesticide residues in fruits and vegetables (see Appendix A) by chromatographic-chromatographic-chromatographic-chromatographic methods.
This standard specifies the determination of 446 kinds of pesticide residues in apples, pears, citrus fruits, grapes, carrots, peaches, oranges, tomatoes, melons, green vegetables, celery, beans, carrots, potatoes, bamboo shoots and other fresh fruits and vegetables. The detection limit of this method is 0.332.2g/kg-0.100mg/kg. See Appendix A2 Normative References
The relevant clauses in the following documents become the clauses of this standard through reference. For all referenced documents with a date of month, their subsequent amendments (excluding date errors) will not be applicable to the revised versions of this standard. However, the latest versions of these documents may be discontinued after the date of this standard is published. For all referenced documents with a date of month, their new versions will be discontinued after the date of this standard expires. 16 Test method and standard test method for laboratory test method with repeatability and reproducibility (G/T 657S-1586.req1S 5725,1961) GB/T 62 Specification for laboratory water and test method (GB/T 5582-102,ne0IS36061987) GB/T 6855 Method for extracting fruits and vegetables (GB/T 9551938.ecJS371:1950) 3 Principle
The sample is extracted with pulp, analyzed by centrifugation, and then taken out for sterilization. After the sample is chemically treated, it is washed with ethyl acetate (No. 11) for one day. According to different test requirements, it is only for liquid chromatography-mass spectrometry. 4 Reagents and materials
Unless otherwise specified in the specification, water is the water specified in GB/TS382. 4.32 Clear: chromatographically pure,
4.2 Sodium chloride: excellent quality.
4.3 Anhydrous sodium sulfate: analytically pure. Use before calcining for 1 hour. Buy in the following device and cool or use later. 4.4 Benzene, excellent quality.
4.5 Propylene: analytically pure, distilled.
4.6 Difluoromethane, chromatographically pure.
Methyl acetate: chromatographically pure.
n-Hydroxyethane analytically pure, redistilled.
Main nvi-8 sample 1.12mL.2.0g or equivalent, 4.93
Envi-Ca: h-encapsulated or column; mT.,t,g or equivalent. 4. 11
Sep-1k main base solid phase extraction: 3I.0.g or equivalent. ) Ea-I and Ev:-C:rb are the product names of the company's products. This is for the convenience of quick reference of the car logo. It does not indicate the approval of the product. If there are other products with the same quality, the product can be selected from the company's products. This information is for the benefit of the users of this logo. It does not indicate the approval of the product. If there are no other products with the same quality, you can use this product. :
GB/T19648—290 yuan
4.2 Pesticide standard quality: purity 3 yuan,
4.13 Pesticide standard solution
2.13.1 Standard stock solution
Weigh the collected pesticide standards (such as C1mR) in 1UL storage bottles, select the solution according to the solution concentration of the standard, such as acetone mixed solution, dichloromethane or alcohol, and adjust the scale (select without A). 4.13.2 Combined standard liquids (combined standard liquids A, D, and E) are divided into eight, D.1: and according to the properties and retention time of the pesticides, determine their concentrations in the conservation standard solution. According to the grouping of pesticides in this book and their labeled concentrations, put two standard liquids A, B, and C in 3mL volumetric flasks of agricultural use according to the number, concentration and retention time of each pesticide. For the preservation of the standard solution, use an internal standard solution of 3.0 mg/ml and take it out of the volumetric flask within a certain period of time. 4.13.3 Internal standard solution Note: Take 3 mg of internal standard solution without oxygen and put it in the volumetric flask within a certain period of time. 4.13.4 The preparation of standard mixed solution of pesticides in groups A, H, L. 1.1 is to add 4:1. Internal standard concentration (1.13.5) 0μT. Standard solution (4..3.2) to 1.nl. Take the sample blank matrix solution and mix well. Prepare the standard mixed solution AB. C, D) The preparation of standard mixed solution of pesticide matrix is ​​not based on the preparation method. The standard mixed solution is prepared immediately. 5. Only the clean color of the sample is retained. 5.) The sample is equipped with an electric source (EI). 5.2 Batch chromatography·mass spectrometer: equipped with electrospray phonon source (K): 5.3 % new: sensitivity 0.1 n6 and 3.01 each. 5.4 High-performance tissue control: transposer 4-axis 2300r: ~/tris5.5 transducer
5. E-machine: speed not less than 4 lil r/uin5.7 heart mE.
5. Daily pipette, 1mL.
5.3 Nitrogen gas only.
5 Preparation and preservation of samples
6. Preparation of samples
Take edible vegetable samples extracted from B: 255% water, cut them into pieces, and mark them as samples. 2 Preservation of samples
Store the sample in a refrigerator.
7 Determination according to the method
7.1 Vibrate
Weigh 30 μg of sample (precise single 2.1R) Fml and insert it into the sample for 20m! BHT, use a tissue crusher at 500/, extract uniformly, add 5 sodium polychloride, extract with carbon dioxide for 1m, put the tubes into two centrifuges, centrifuge at 00r:min, take 20ml of supernatant (equivalent to 10ml) for purification: 7.2 Purification
GH/T19648—2005
7.2.1A.BC1 group: put vi18 cattle into fixed rack F.7.2.2. Transfer 100 mL of lipid pre-wash solution to the top of the chicken heart, and then transfer 3 mL of the extract to about 1 mL of the following group. 7.2.3. Add about 1 mL of anhydrous trichloroethane to a height of about 2 cm in a silver bath, and connect the sample to the nitrogen prep section of the ScP-Pak, and move the sample to the holder at the back of the bottle. 7.2.1. Pre-wash the sample with 4 mL of lipid extract (3, 1). When the sample reaches the lower end, slowly release the sample and do the following: .2.2) Transfer to the purification chamber: wash the sample with 2 tons of ethyl acetate each time for a total of 3-1 times. Store the sample in a tray and add 1:5) 1 mL of ethanol to the tandem rod. Elute the drug with 1 mL of ethanol (3+1) and add 0.5% water to the solution. For the 2B and C group drugs, add 5 mL of ethane each time and rotate in a water bath. Change the solution several times until the solution volume is about 1 mL. The mixture can be used for gas chromatography-mass spectrometry (GC-MS). Place the concentrated drug in a 3-2 mL atmosphere and blow it with ethyl acetate + water for a total of 1 mL. Determine by pressure chromatograph-mass spectrometry. 7.3. 7.3. 1 Gas chromatography-mass spectrometry 7.3. 1 Strip
Color error: Industry 01 (X0.25m×25 case or material: free spectrum for temperature electricity: keep mn and then increase the temperature by in. Then increase the temperature by 5:mr at a temperature rate of 25 and then increase the temperature by n to 3 and keep 5mn:
I gas::. Send mlmin
Through Xiangkou full: 2SC:
Reverse method: large separation to avoid the fence, 1.mir: after the split flow wide two times sweep valve: L Guangsen hit source: eV:
Business source tour 28
Heart -MS temperature 1 28 ℃ || tt || select the monitoring pass: then select a quantitative separation for each compound, 2 ~ 1 actual separation, each sample has to be tested according to the number of shares, respectively. Long compound warranty quantitative separation, qualitative separation: quantitative with the material will be measured according to the high frequency of the son of the appendix year and the retention time see appendix 7.3.1.2 qualitative determination || tt || for product determination period inspection book color full frequency ratio retention time can be the same standard, the quantity is clearing the background If the selected ions are compared with the standard sample, the sample can be kept in the column. If it cannot be confirmed, a new sample can be injected, and the result can be confirmed by scanning or capturing (with sufficient sensitivity) or by using a more sensitive mass spectrometer. 7.3.1.3 Quantitative determination
In order to achieve the desired result, the internal standard method is used as the single drink. To reduce the influence of H quality, the internal standard method should be replaced with chlorine: to ensure that the standard matrix is ​​not mixed, the sample should be injected again. Standard. Working principle: The concentration of the standard should be close to that of the chemical to be tested. The four groups of standard substances A, H, C, are separated and measured by G-MS. See 73.2. Standard chromatography-mass spectrometry. 7.3.2.1 Conditions: Color column: Allanm.3rr, 5mx, 1m or equivalent: Temperature: 1: Injection 1: 20: GB/T 19648—2005
Sweep mode, positive ion scan:
Measurement mode: rate change test!
Electrospray voltage 0
Main gas pressure: 3.076MPe:
Curtain gas: 0.C3MP
Gas velocity: eL/rmin
Ion source temperature: 350℃
Monitor high ion pair, shift energy and de-energization, see Appendix E attenuation current Phase and flow rate
time: uin
7.3.2.2 Qualitative determination
.mir.>
The product is read through the projection chromatography and the mass spectrometer is connected to the measurement unit for each component to be measured separately. When the sample is selected for measurement, if the retention time of the calibrated chromatogram is consistent with that of a certain matrix marker, and the ratio of the two selected pairs of separations is consistent, it is called determination that this retention time exists in the sample.
7. 3. 2. 3 Quantitative determination
In this method, the liquid chromatography-tandem mass spectrometry is used to quantify the sample by external standard method. In order to reduce the influence of the base on the determination, a series of base pressure standard working solutions are prepared with blank sample solution, and the standard working solution is used to prepare the standard line + and ensure that the measured sample is within the linear cell pressure of the instrument: The E group standard substances detected by this method are shown in the TC-MSMS.
71 Parallel test
Carry out parallel test on the same sample according to the above steps. 7.5 Blank test
Except that the test sample is not weighed, all the above steps are carried out. Calculation of results
8.1 Gas chromatograph - internal standard method automatic calculation, according to the formula (1 calculation, AAxxx
sample analyte concentration unit is per point (k2 sample dark liquid micro-area
matrix mixed standard working solution peak area of ​​internal standard in the sample water;
matrix standard working solution concentration of analyte, unit is g per liter (g.1); 1
one mass standard is the internal standard in the liquid, unit is g per liter (sample) The internal standard is added to the solution. The unit is microgram; the non-standard substance represents the amount of the sample, the unit is grams: GR/T19628-2035
2 Full-scale chromatography-mass spectrometry uses standard blood for determination. The standard blood results are calculated according to the formula: 8.2
x—the measured component of the sample: the unit is grams (/kg)—the measured component concentration obtained from the standard, expressed as grams (limited to mL sample solution, unit is mL)
9 Precision tester
The mass of the sample solution represented by the test substance, the unit is (2
Standard test number The data are determined according to the provisions of (3/T6373, the values ​​of the cost and currency or the minimum confidence level are calculated with a 95% minimum confidence level. For the specifications of this standard method, please refer to Appendix G. GB/T19648-2CCE
1. Informative Appendix)
Table of Chinese and English names, method detection limits, groups, solvent selection and concentration of combined standard solutions of 446 pesticides. Table of Chinese and English names, method detection limits, groups, solvent selection and concentration of combined standard solutions of 446 pesticides. See Table A. Table of Chinese and English names, method detection limits, groups, solvent selection and concentration of combined standard solutions of 1446 pesticides. ||French standard!
Give inner yarn sex glue
Know the disease class
Environmental production micro
21 rat wine
City base calculation
Five pairs of elimination to luck
7. Bi Atra God
One sea road
For the regulation
7.Limited elegant
On the Bingshu production
Since the European
English multi-name
[Iuptaslifor-cpxoxide
Jurhlinrnn
FEt-idiazol
t.nlorep lu
tgr: aalr
Inphenglyui'm
Ch.u.cu.e.oi.n
ElhaHlLrsn
Plruate
Thicmeter
Quinrczelt
Srr.zit s-dhy
Cl-riasong
Ppe Laiplae
Sechuaueluri
ieldcteulio
6, coe 3
.312 5
This Ba Shao
Ci Lang (+
Sheep! Bing!
Inside:-
Form standard get the core of the machine
of the core
six six six
in the bottom
six six six
Liu Huaxiao
Li Zu Chen
B point exchange thank you
This light and fast
and Point leading pill
now the whole clinical
inside reading group
lack of Shi Run
please resign to
kill the fall
education, foreign
bitter Han effect
individual period of suffering from superior
kill roast special
table A,1 continuation
English name road
Vixi:zoli:t
Beta [iC.H
Metalaxyl
(alorpyrifes : =hyl)
Vethyl-P'atataipn
Artarauinve
Mal.rainn
[eui.Jo.hicn
Pg:a>l -lyl
Itiac.u.nion
Paatiou
Pel.J.uzths.in
Clhrbensile
Prulpw.oeti?
Cunit.gr.
r rp.ikidoue
Paarn.latr
M axin?
Feanh.arb
..sle.fi.rpl
Tar iclrn
Prynl:
M+-fie: :ht-r
Cynnzn
Ma snepnmihe
T,brnd nar:Tu
Annire
Detection limit:
. t2 4
. 316
. 31R 2
.:. x5 3
GB/T19646—2C05
Who meets the standard of deep distribution
According to the bottom/(ne:
二源小元
内8+1
·丙刚—)
CB/T 19648-- 2005
Hydroxyamine
Chinese famous medicine
Xiaorunyou
Guiliangdu
Buzoto1
Long Lidong
Joint extraction medicine
Shenyuetang
A-flow Yanji
Fear of light welcome
Winzocosol
Oh Nanping
Industry brain section
Ershabu
Oxidation shows hammer hot
Aoqinaide
With grass enemy
Xiacao enemy
Table A.1 (lock)
Flutelazil
Ctaion
Sulproos
E't.engazole :
E1aeonaxple-2
Myelebutan!
Dic.oo-rcthyl
Prapitisagole
Feriullutiu
Bientluiu
Hiraruitl.arel
Naarmil
Mrihnky hl:sr
kadixyl
Iet-nm:ur
Tehurnnzxle
N:rflnrnzr:
W'yt nnphrniha.n
Ionsnke
Tetndhi'r:n
Giryantwrir.
is-Pr+Tthsir.||tt ||Pyraraphne
Gspctmrthrin
Feniveicre\e
1clgmhrn
Bcglatt
! Tacnlesxenid
Risk limit:
Enn:kni
3, 515 8
5, 366 3
. c2i
Stop hexane
（9+1）
A-1 internal work (（9+1）
Wenlu Xiezhun Shen
Depth: (ng/)
Serial number, group number
Kecao reform
Chinese name selection
Trichlorobenzidine
Di Maosan
Four-inspired sales. Standard
Gray pregnancy level
Dawei Yan
Destroy the line class
Muscle style photo female enemy
Chengshi source change music|| tt||oxychloride
floating with the spirit
snail treatment device
special T road
circular effect,
puwenti
new demon release
elephant stepping on sleep
liang ronglu
ideal insect music
killing frequency head
hand even with dead axis
diquat
one year hospital
a complete connection
methyl thiazide
etc."clean
haicaodan
table A, 1 continued)
无文名
Pesrlare
Niurapy-us
Mevinpbos
Cloroeb
Tecoaznne
Eep1swpbus
Hexachl.saher xene
Ethneiybos
zis-Dral:atr
['torgchlel
t:ns-1.al.ale
CLiorprplau
SLforep
SLallate
Alμla HCH
Teilufue
Terhwain
Pr.[luralar
Pnigain
Didoraa
Trbuatbylax ni:
Mcnkiamun
FluEcnnwi:
C:yunephr:
(hn\lyr- frmrthyl
Tksmr-rym
Dine-fnntle-r
Alarhlar
Pirimiphog 312 b
.c26 3
3. ±15 8
CB/T 196482005
Concentration: (mg:.)
+Nei-13
Indian·Nei (812)ikidoue
Paarn.latr
M axin?
Feanh.arb
..sle.fi.rpl
Tar iclrn
Prynl:
snepnmihe
T,brnd nar:Tu
Annire
Detection limit:
. t2 4
. 316
. 31R 2
.:. x5 3
GB/T19646—2C05
Who meets the standard of deep distribution
According to the bottom/(ne:
Two source small element
Inside 8+1
·Binggang—)
CB/T 19648-- 2005
Hydroxyamine
Chinese famous medicine
Xiaorunyou
Guiliangdu
Buzoto1
Long Lidong
Joint extraction medicine
Shenyuetang
A-flow Yanji
Fear of light welcome
Winzocosol
Oh Nanping
Industry brain section
Ershabu
Oxidation shows hammer hot
Aoqinaide
With grass enemy
Xiacao enemy
Table A.1 (lock)
Flutelazil
Ctaion
Sulproos
E't.engazole :
E1aeonaxple-2
Myelebutan!
Dic.oo-rcthyl
Prapitisagole
Feriullutiu
Bientluiu
Hiraruitl.arel
Naarmil
Mrihnky hl:sr
kadixyl
Iet-nm:ur
Tehurnnzxle
N:rflnrnzr:
W'yt nnphrniha.n
Ionsnke
Tetndhi'r:n
Giryantwrir.
is-Pr+Tthsir.||tt ||Pyraraphne
Gspctmrthrin
Feniveicre\e
1clgmhrn
Bcglatt
! Tacnlesxenid
Risk limit:
Enn:kni
3, 515 8
5, 366 3
. c2i
Stop hexane
（9+1）
A-1 internal work (（9+1）
Wenlu Xiezhun Shen
Depth: (ng/)
Serial number, group number
Kecao reform
Chinese name selection
Trichlorobenzidine
Di Maosan
Four-inspired sales. Standard
Gray pregnancy level
Dawei Yan
Destroy the line class
Muscle style photo female enemy
Chengshi source change music|| tt||oxychloride
floating with the spirit
snail treatment device
special T road
circular effect,
puwenti
new demon release
elephant stepping on sleep
liang ronglu
ideal insect music
killing frequency head
hand even with dead axis
diquat
one year hospital
a complete connection
methyl thiazide
etc."clean
haicaodan
table A, 1 continued)
无文名
Pesrlare
Niurapy-us
Mevinpbos
Cloroeb
Tecoaznne
Eep1swpbus
Hexachl.saher xene
Ethneiybos
zis-Dral:atr
['torgchlel
t:ns-1.al.ale
CLiorprplau
SLforep
SLallate
Alμla HCH
Teilufue
Terhwain
Pr.[luralar
Pnigain
Didoraa
Trbuatbylax ni:
Mcnkiamun
FluEcnnwi:
C:yunephr:
(hn\lyr- frmrthyl
Tksmr-rym
Dine-fnntle-r
Alarhlar
Pirimiphog 312 b
.c26 3
3. ±15 8
CB/T 196482005
Concentration: (mg:.)
+Nei-13
Indian·Nei (812)ikidoue
Paarn.latr
M axin?
Feanh.arb
..sle.fi.rpl
Tar iclrn
Prynl:
snepnmihe
T,brnd nar:Tu
Annire
Detection limit:
. t2 4
. 316
. 31R 2
.:. x5 3
GB/T19646—2C05
Who meets the standard of deep distribution
According to the bottom/(ne:
Two source small element
Inside 8+1
·Binggang—)
CB/T 19648-- 2005
Hydroxyamine
Chinese famous medicine
Xiaorunyou
Guiliangdu
Buzoto1
Long Lidong
Joint extraction medicine
Shenyuetang
A-flow Yanji
Fear of light welcome
Winzocosol
Oh Nanping
Industry brain section
Ershabu
Oxidation shows hammer hot
Aoqinaide
With grass enemy
Xiacao enemy
Table A.1 (lock)
Flutelazil
Ctaion
Sulproos
E't.engazole :
E1aeonaxple-2
Myelebutan!
Dic.oo-rcthyl
Prapitisagole
Feriullutiu
Bientluiu
Hiraruitl.arel
Naarmil
Mrihnky hl:sr
kadixyl
Iet-nm:ur
Tehurnnzxle
N:rflnrnzr:
W'yt nnphrniha.n
Ionsnke
Tetndhi'r:n
Giryantwrir.
is-Pr+Tthsir.||tt ||Pyraraphne
Gspctmrthrin
Feniveicre\e
1clgmhrn
Bcglatt
! Tacnlesxenid
Risk limit:
Enn:kni
3, 515 8
5, 366 3
. c2i
Stop hexane
（9+1）
A-1 internal work (（9+1）
Wenlu Xiezhun Shen
Depth: (ng/)
Serial number, group number
Kecao reform
Chinese name selection
Trichlorobenzidine
Di Maosan
Four-inspired sales. Standard
Gray pregnancy level
Dawei Yan
Destroy the line class
Muscle style photo female enemy
Chengshi source change music|| tt||oxychloride
floating with the spirit
snail treatment device
special T road
circular effect,
puwenti
new demon release
elephant stepping on sleep
liang ronglu
ideal insect music
killing frequency head
hand even with dead axis
diquat
one year hospital
a complete connection
methyl thiazide
etc."clean
haicaodan
table A, 1 continued)
无文名
Pesrlare
Niurapy-us
Mevinpbos
Cloroeb
Tecoaznne
Eep1swpbus
Hexachl.saher xene
Ethneiybos
zis-Dral:atr
['torgchlel
t:ns-1.al.ale
CLiorprplau
SLforep
SLallate
Alμla HCH
Teilufue
Terhwain
Pr.[luralar
Pnigain
Didoraa
Trbuatbylax ni:
Mcnkiamun
FluEcnnwi:
C:yunephr:
(hn\lyr- frmrthyl
Tksmr-rym
Dine-fnntle-r
Alarhlar
Pirimiphog 312 b
.c26 3
3. ±15 8
CB/T 196482005
Concentration: (mg:.)
+Nei-13
Indian·Nei (812)
is-Pr+Tthsir.
Pyraraphne
Gspctmrthrin
Feniveicre\e
1clgmhrn
Bcglatt
! Tacnlesxenid
Risk limit:
Enn:kni
3, 515 8
5, 366 3
. c2i
Stop hexane
（9+1）
A-1 internal work (（9+1）
Wenlu Xiezhun Shen
Depth: (ng/)
Serial number, group number
Kecao reform
Chinese name selection
Trichlorobenzidine
Di Maosan
Four-inspired sales. Standard
Gray pregnancy level
Dawei Yan
Destroy the line class
Muscle style photo female enemy
Chengshi source change music|| tt||oxychloride
floating with the spirit
snail treatment device
special T road
circular effect,
puwenti
new demon release
elephant stepping on sleep
liang ronglu
ideal insect music
killing frequency head
hand even with dead axis
diquat
one year hospital
a complete connection
methyl thiazide
etc."clean
haicaodan
table A, 1 continued)
无文名
Pesrlare
Niurapy-us
Mevinpbos
Cloroeb
Tecoaznne
Eep1swpbus
Hexachl.saher xene
Ethneiybos
zis-Dral:atr
['torgchlel
t:ns-1.al.ale
CLiorprplau
SLforep
SLallate
Alμla HCH
Teilufue
Terhwain
Pr.[luralar
Pnigain
Didoraa
Trbuatbylax ni:
Mcnkiamun
FluEcnnwi:
C:yunephr:
(hn\lyr- frmrthyl
Tksmr-rym
Dine-fnntle-r
Alarhlar
Pirimiphog m:cthsl
TehJty
Thiobencant
乐出 limit
. G3e
.C16 3
. 312 b
.c26 3
3. ±15 8
CB/T 196482005
Concentration: (mg:.)
+Nei-13
Indian·Nei (812)
is-Pr+Tthsir.
Pyraraphne
Gspctmrthrin
Feniveicre\e
1clgmhrn
Bcglatt
! Tacnlesxenid
Risk limit:
Enn:kni
3, 515 8
5, 366 3
. c2i
Stop hexane
（9+1）
A-1 internal work (（9+1）
Wenlu Xiezhun Shen
Depth: (ng/)
Serial number, group number
Kecao reform
Chinese name selection
Trichlorobenzidine
Di Maosan
Four-inspired sales. Standard
Gray pregnancy level
Dawei Yan
Destroy the line class
Muscle style photo female enemy
Chengshi source change music|| tt||oxychloride
floating with the spirit
snail treatment device
special T road
circular effect,
puwenti
new demon release
elephant stepping on sleep
liang ronglu
ideal insect music
killing frequency head
hand even with dead axis
diquat
one year hospital
a complete connection
methyl thiazide
etc."clean
haicaodan
table A, 1 continued)
无文名
Pesrlare
Niurapy-us
Mevinpbos
Cloroeb
Tecoaznne
Eep1swpbus
Hexachl.saher xene
Ethneiybos
zis-Dral:atr
['torgchlel
t:ns-1.al.ale
CLiorprplau
SLforep
SLallate
Alμla HCH
Teilufue
Terhwain
Pr.[luralar
Pnigain
Didoraa
Trbuatbylax ni:
Mcnkiamun
FluEcnnwi:
C:yunephr:
(hn\lyr- frmrthyl
Tksmr-rym
Dine-fnntle-r
Alarhlar
Pirimiphog m:cthsl
TehJty
Thiobencant
乐出 limit
. G3e
.C16 3
. 312 b
.c26 3
3. ±15 8
CB/T 196482005
Concentration: (mg:.)
+Nei-13
Indian·Nei (812)
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